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Chemistry · Glossary

What is Lattice, motif, unit cell?

Also known as: lattice · node · motif · unit cell · lattice parameters

Definition 5.2 University Chemistry — Year 1 · Chapter 5 — Crystals I: The Perfect Crystal and Metals

A lattice is an infinite set of points, the nodes, obtained from one of them by all the translations u a⃗+v b⃗+w c⃗u\,\vec a + v\,\vec b + w\,\vec c with integer uu, vv, ww. The crystal is obtained by placing on every node the same motif (one atom, a group of atoms or ions). A unit cell is a parallelepiped built on a⃗\vec a, b⃗\vec b, c⃗\vec c whose translations fill space; its edge lengths and angles are the lattice parameters aa, bb, cc, α\alpha, β\beta, γ\gamma. In a cubic cell a=b=ca = b = c and the angles are 90∘90^\circ.

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