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Chemistry · Glossary

What is Solvation, ionising and dissociating power?

Also known as: solvation · ionising power · dissociating power

Definition 4.10 University Chemistry — Year 1 · Chapter 4 — Intermolecular Forces and Solvents

The solvation of a solute particle is its surrounding by solvent molecules oriented and bound to it by intermolecular forces (hydration, in water). The ionising power of a solvent is its ability to turn a polar covalent bond of the solute into an ion pair, a property of polar solvents with a large dipole moment; its dissociating power is its ability to separate the ions of a pair, measured by its relative permittivity.

Examples

Example 4.12 (Hydrogen chloride in water and in hexane)

In water, HCl\ce{HCl} is ionised and dissociated completely: HCl(g)+HX2O(l)→HX3OX+(aq)+ClX−(aq)\ce{HCl(g) + H2O(l) -> H3O+(aq) + Cl-(aq)}; the solution conducts. In hexane, apolar and of low permittivity, it dissolves as HCl\ce{HCl} molecules and the solution does not conduct.

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