All books

Professional

Apps About Coach Log in Start reading

Chemistry · Glossary

What is Stoichiometric numbers, extent?

Also known as: stoichiometric number · extent of reaction

Definition 7.6 University Chemistry — Year 1 · Chapter 7 — Describing a Chemical System: Extent, Activities, Q and K

A reaction is written 0=∑iνi Ai0 = \sum_i \nu_i\,\mathrm{A}_i, where the stoichiometric number νi\nu_i of species Ai\mathrm{A}_i is negative for a reactant and positive for a product: in NX2+3 HX2→2 NHX3\ce{N2 + 3H2 -> 2NH3}, ν(NX2)=−1\nu(\ce{N2}) = -1, ν(HX2)=−3\nu(\ce{H2}) = -3, ν(NHX3)=+2\nu(\ce{NH3}) = +2. In a closed system where this reaction alone takes place, the amounts change as

ni=ni,0+νi ξ,n_i = n_{i,0} + \nu_i\,\xi ,

which defines the extent of reaction ξ\xi (in moles), zero at the start and the same for every species.

Read in context →