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Chemistry · Glossary

What is Electron affinity?

Definition 2.13 University Chemistry — Year 1 · Chapter 2 — Periodicity

The electron affinity EeaE_{ea} of an element is the energy released when an isolated atom in its ground state captures an electron in the gas phase,

X(g)+eX−→XX−(g),Eea=E(X)+E(eX−)−E(XX−).\ce{X(g) + e- -> X-(g)}, \qquad E_{ea} = E(\ce{X}) + E(\ce{e-}) - E(\ce{X-}) .

It is positive when the anion is more stable than the atom and the free electron.

Examples

Example 2.14 (Halogens and their neighbours)

The electron affinities of F\ce{F}, Cl\ce{Cl}, Br\ce{Br} and I\ce{I} are 3.40, 3.61, 3.36 and 3.06 eV3.06\,\mathrm{eV}, the largest of all elements; those of O\ce{O} and S\ce{S} are 1.44 and 2.02 eV2.02\,\mathrm{eV}, of C\ce{C} 1.26 eV1.26\,\mathrm{eV}, of Na\ce{Na} 0.55 eV0.55\,\mathrm{eV}. Atoms that complete a subshell by capturing an electron (the halogens) release much energy. Nitrogen, beryllium, magnesium and the noble gases form no stable gaseous anion: the extra electron would have to pair in a half-filled p subshell or enter a new subshell. Fluorine’s affinity is smaller than chlorine’s because the added electron is crowded into the small 2p shell.

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