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Chemistry · Glossary

What is Alcohol, class of an alcohol?

Also known as: alcohol · class of an alcohol

Definition 33.2 School Chemistry — Grades 1 to 12 · Chapter 33 — Functional Groups and Families

An alcohol has a hydroxyl group −OH\ce{-OH} bonded to a carbon atom that has only single bonds. The class of an alcohol is primary, secondary or tertiary according to whether the carbon atom bearing the −OH\ce{-OH} is bonded to one, two or three other carbon atoms. (Methanol, CHX3OH\ce{CH3OH}, whose carbon is bonded to none, is counted with the primary alcohols.)

Three isomers C4H10O, three classes of alcohol.
Three isomers CX4HX10O\ce{C4H10O}, three classes of alcohol.

Examples

Example 33.5 (Ethyl ethanoate)

The solvent ethyl ethanoate, CHX3−COO−CHX2−CHX3\ce{CH3-COO-CH2-CH3}, smells of pear drops and nail-varnish remover. Its “acid part”, CHX3−CO\ce{CH3-CO}, comes from ethanoic acid CHX3−COOH\ce{CH3-COOH} and gives the second word of the name, ethanoate; its “alcohol part”, O−CHX2−CHX3\ce{O-CH2-CH3}, comes from ethanol CHX3−CHX2−OH\ce{CH3-CH2-OH} and gives the first word, ethyl. A later chapter shows how an ester is made from its acid and its alcohol.

Example 33.10 (Four names)

is propan-2-ol (a secondary alcohol); is butan-2-one; is butanoic acid; is 3-methylbutanal.

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