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Chemistry · Glossary

What is Amount of substance and mole?

Also known as: amount of substance · mole

Definition 25.3 School Chemistry — Grades 1 to 12 · Chapter 25 — The Mole and Molar Mass

The amount of substance nn of a sample counts the entities it contains (atoms, molecules or ions, stated each time). Its unit is the mole, symbol mol\mathrm{mol}: one mole contains exactly 6.022 140 76×10236.022\,140\,76 \times 10^{23} entities.

Examples

Example 25.10 (One mole of carbon atoms)

An atom of carbon-12 has a mass of about 12×1.67×10−27 kg=2.00×10−26 kg12 \times 1.67 \times 10^{-27}\,\mathrm{kg} = 2.00 \times 10^{-26}\,\mathrm{kg}. One mole of them has a mass of

2.00×10−26 kg×6.02×1023=1.20×10−2 kg=12.0 g.2.00 \times 10^{-26}\,\mathrm{kg} \times 6.02 \times 10^{23} = 1.20 \times 10^{-2}\,\mathrm{kg} = 12.0\,\mathrm{g}.

The mole has been chosen so that the molar mass of an atom, in grams per mole, is close to its mass number: about 1 g/mol1\,\mathrm{g}/\mathrm{mol} for hydrogen, 12 g/mol12\,\mathrm{g}/\mathrm{mol} for carbon, 16 g/mol16\,\mathrm{g}/\mathrm{mol} for oxygen.

Example 25.17 (A mole on the bench)

One mole of water is 18.0 g18.0\,\mathrm{g}, about a tablespoon. One mole of salt, 58.5 g58.5\,\mathrm{g}, is a small heap; one mole of sugar, 342.0 g342.0\,\mathrm{g}, fills a mug; one mole of iron, 55.8 g55.8\,\mathrm{g}, is a cube a little under 2 cm2\,\mathrm{cm} across. All four hold the same number of entities: the molecules of sugar are simply much heavier than those of water, and the atoms of iron are packed much more tightly.

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