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Chemistry · Glossary

What is Hermitian operator, expectation value?

Also known as: Hermitian operator · expectation value

Definition 1.3 University Chemistry — Year 3 · Chapter 1 — Quantum Mechanics for Chemists: Model Systems

Write ⟨f∣g⟩=∫f∗g  ⁣dτ\langle f|g\rangle = \int f^*g\,\dd\tau for two functions that vanish at the boundaries of the region. An operator is Hermitian if ⟨f∣A^g⟩=⟨A^f∣g⟩\langle f|\hat Ag\rangle = \langle \hat Af|g\rangle for all such ff and gg. For a normalised state ψ\psi (⟨ψ∣ψ⟩=1\langle\psi|\psi\rangle = 1), the expectation value of A^\hat A is ⟨A⟩=⟨ψ∣A^ψ⟩\langle A\rangle = \langle\psi|\hat A\psi\rangle: the mean of many measurements made on identically prepared systems.

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