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Chemistry · Glossary

What is Lewis acid, Lewis base, dative bond?

Also known as: Lewis acid · Lewis base · dative bond

Definition 3.8 University Chemistry — Year 1 · Chapter 3 — Lewis Structures, Resonance and VSEPR

A Lewis acid is a species able to accept a pair of electrons into a vacant place of its valence shell (BFX3\ce{BF3}, AlClX3\ce{AlCl3}, HX+\ce{H+}, metal cations); a Lewis base is a species with a lone pair it can share (NHX3\ce{NH3}, HX2O\ce{H2O}, FX−\ce{F-}). When the base gives the pair to the acid, the bond formed is a dative bond: a covalent bond whose two electrons both came from one partner.

A dative bond: the lone pair of ammonia (a Lewis base) fills the vacant place of boron trifluoride (a Lewis acid). Lone pairs of fluorine are not drawn.
A dative bond: the lone pair of ammonia (a Lewis base) fills the vacant place of boron trifluoride (a Lewis acid). Lone pairs of fluorine are not drawn.

Examples

Example 3.9 (Ammonia and boron trifluoride)

NHX3+BFX3→HX3NBFX3\ce{NH3 + BF3 -> H3NBF3}. In the adduct, boron completes its octet; nitrogen, which now shares its lone pair, carries the formal charge +1+1 and boron −1-1. Once formed, the N−B\ce{N-B} bond is an ordinary covalent bond.

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