Example 5.10(The combinations of ammonia and water)
In NHX3, P^A1h1∝h1+h2+h3 (all characters 1). For E (characters2,−1,0), P^Eh1∝2h1−h2−h3; projecting h2 and orthogonalising gives the partner h2−h3. Normalised: a1=31(h1+h2+h3), e=61(2h1−h2−h3), 21(h2−h3). In HX2O, placed in the xz plane, h1+h2 is a1 and h1−h2 is b1 (it changes sign under C2 and under σv′(yz), which exchange the hydrogens). With the molecule in the yz plane, as some books prefer, the labels b1 and b2 are exchanged throughout.