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Chemistry · Glossary

What is Reaction coordinate, energy profile, transition state?

Also known as: reaction coordinate · energy profile · transition state

Definition 9.4 University Chemistry — Year 1 · Chapter 9 — Reaction Mechanisms: Elementary Steps and Approximations

Along an elementary step the atoms move from the arrangement of the reactants to that of the products; a variable that measures this progress (a bond length that grows, another that shrinks) is the reaction coordinate. The graph of the potential energy of the system along it is the energy profile. Its maximum is the transition state, an arrangement of the atoms with bonds half-made and half-broken, which lasts no longer than a molecular vibration and cannot be isolated. The height of this maximum above the reactants is the energy barrier of the step.

Left: the profile of one elementary step, with its barrier and the energy change of the reaction. Right: a two-step mechanism; the intermediate sits in a hollow between two transition states. The energies are illustrative.
Left: the profile of one elementary step, with its barrier and the energy change of the reaction. Right: a two-step mechanism; the intermediate sits in a hollow between two transition states. The energies are illustrative.
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