Let light travel in a medium of index toward a medium of smaller index . The critical angle is the angle of incidence for which the refracted ray grazes the surface (). For no refracted ray exists: the surface reflects all the light back into the first medium, following the law of reflection. This is total internal reflection.
Examples
Example 3.18 (Three critical angles)
Toward air: for water, , so ; for glass, , so ; for diamond, , so . The higher the index, the narrower the escape cone: in diamond, any ray more than off a facet’s normal is trapped — the secret of its sparkle, dissected in Problem 3.1.