is the cost, in free energy, of adding one particle at fixed and . Particles flow spontaneously from high to low — diffusion, osmosis, evaporation, chemical reactions and electric currents are all -gradients relaxing. At equilibrium between any two phases or places, is equal on both sides — the third equality (with and ) that governs coexistence. For a classical ideal gas,
adding a particle to a dilute gas lowers the free energy, because the entropy gain outweighs any energy cost — the sign that drives evaporation into dry air. And a battery is a -machine: its voltage is the chemical-potential drop per electron between its electrodes, — volts are electron chemistry’s exchange rate, which is why cells deliver single-digit volts.