Physics · Glossary

What is What μ means?

Definition 18.2 University Physics — Year 3 · Chapter 18 — The Grand Canonical Ensemble

μ\mu is the cost, in free energy, of adding one particle at fixed TT and VV. Particles flow spontaneously from high μ\mu to low μ\mu — diffusion, osmosis, evaporation, chemical reactions and electric currents are all μ\mu-gradients relaxing. At equilibrium between any two phases or places, μ\mu is equal on both sides — the third equality (with TT and PP) that governs coexistence. For a classical ideal gas,

μ=kBTln ⁣(nλT3)<0(dilute gas):\mu = k_{\text{B}}T\,\ln\!\big(n\lambda_T^3\big) < 0 \quad\text{(dilute gas)} :

adding a particle to a dilute gas lowers the free energy, because the entropy gain outweighs any energy cost — the sign that drives evaporation into dry air. And a battery is a μ\mu-machine: its voltage is the chemical-potential drop per electron between its electrodes, U=Δμ/eU = \Delta\mu/e — volts are electron chemistry’s exchange rate, which is why cells deliver single-digit volts.

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