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Chemistry · Glossary

What is Degenerate levels?

Also known as: degeneracy

Definition 1.14 University Chemistry — Year 3 · Chapter 1 — Quantum Mechanics for Chemists: Model Systems

Linearly independent eigenfunctions with the same eigenvalue are degenerate levels; their number is the degeneracy gg of that energy.

Examples

Example 1.15 (Degeneracy and symmetry)

The level nx2+ny2+nz2=6n_x^2 + n_y^2 + n_z^2 = 6 of the cube comes from (2,1,1)(2,1,1), (1,2,1)(1,2,1) and (1,1,2)(1,1,2): g=3g = 3. Stretch the box slightly along zz and the third function moves away from the other two: the degeneracy came from the symmetry of the cube. The same link between symmetry and degeneracy organises Chapters 4 and 5.

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