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Chemistry · Glossary

What is Duet and octet rules?

Also known as: duet rule · octet rule

Definition 23.8 School Chemistry — Grades 1 to 12 · Chapter 23 — Electron Shells and the Periodic Table

The noble gases, with a full outer shell, hardly react: their configuration is especially stable. When atoms of the first elements form ions, they gain or lose electrons so as to reach the configuration of the nearest noble gas: two electrons in shell 1, like helium, for the lightest atoms — the duet rule — and eight electrons in the outer shell, like neon or argon, for the others — the octet rule.

The sodium ion has the configuration of neon, the nearest noble gas.
The sodium ion has the configuration of neon, the nearest noble gas.

Examples

Example 23.9 (Ions predicted by the rule)

Sodium, 2.8.12.8.1, loses its single valence electron: NaX+\ce{Na+}, 2.82.8, like neon. Magnesium, 2.8.22.8.2, loses two: MgX2+\ce{Mg^{2+}}. Aluminium, 2.8.32.8.3, loses three: AlX3+\ce{Al^{3+}}. Chlorine, 2.8.72.8.7, gains one: ClX−\ce{Cl-}, 2.8.82.8.8, like argon. Oxygen, 2.62.6, gains two: OX2−\ce{O^{2-}}. Sulfur, 2.8.62.8.6: SX2−\ce{S^{2-}}. Lithium, 2.12.1, loses one and keeps 22, like helium: LiX+\ce{Li+}.

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