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Chemistry · Glossary

What is Rigid rotor, spherical harmonics?

Also known as: rigid rotor · spherical harmonics

Definition 1.23 University Chemistry — Year 3 · Chapter 1 — Quantum Mechanics for Chemists: Model Systems

A rigid rotor is a body of fixed shape turning freely; for a linear molecule, H^=L^2/2I\hat H = \hat L^2/2I, where L^2\hat L^2 is the operator of the square of the angular momentum. Its eigenfunctions, which depend only on the angles θ\theta and ϕ\phi, are the spherical harmonics Yl,m(θ,ϕ)Y_{l,m}(\theta,\phi), labelled by l=0,1,2,…l = 0, 1, 2, \dots and m=−l,…,lm = -l, \dots, l; for a molecule ll is written JJ.

The first levels of a linear rigid rotor, E_J = J(J+1)\, 2/2I, with their degeneracies 2J + 1. The gaps grow as 2(J+1): the reason for the evenly spaced lines of .
The first levels of a linear rigid rotor, EJ=J(J+1) ℏ2/2IE_J = J(J+1)\,\hbar^2/2I, with their degeneracies 2J+12J + 1. The gaps grow as 2(J+1)2(J+1): the reason for the evenly spaced lines of Chapter 6.
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