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Chemistry · Glossary

What is Screw axis, glide plane, space group?

Also known as: screw axis · glide plane · space group · asymmetric unit · Wyckoff position

Definition 9.15 University Chemistry — Year 3 · Chapter 9 — Crystallography and X-ray Diffraction

A screw axis npn_p combines a rotation by 2π/n2\pi/n with a translation of p/np/n of the lattice repeat along the axis (212_1: half a turn and half a cell). A glide plane combines a reflection with a translation of half a lattice vector parallel to the plane (aa, bb, cc glides). The group of all the symmetry operations of a crystal, translations included, is its space group: there are 230. Its smallest part from which the whole crystal is generated by the operations is the asymmetric unit. A set of points left on themselves by a subgroup of the operations is a Wyckoff position: general positions have no symmetry, special positions lie on symmetry elements.

The space group P2_1/c seen along c (projection on the ab plane). Dotted lines: c-glide planes perpendicular to b; half-arrows: 2_1 screw axes along b (at height z = 1/4); small circles: centres of inversion. A general position at height +z generates three others; a comma marks a mirror-image copy (produced by the glide or the inversion); 1/2- means height 1/2 - z.
The space group P21/c2_1/c seen along cc (projection on the abab plane). Dotted lines: cc-glide planes perpendicular to bb; half-arrows: 212_1 screw axes along bb (at height z=14z = \frac14); small circles: centres of inversion. A general position at height +z+z generates three others; a comma marks a mirror-image copy (produced by the glide or the inversion); 12−\frac12{-} means height 12−z\frac12 - z.
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